Epub 2009 Jan 15. The method eliminates the need to use a cuvet or large quantities of samples and reagents. The synergistic effects of different enhancement approaches are illustrated by the determination of lead by FAAS using an FI coprecipitation preconcentration system equipped with a slotted-tube atom trap. A 500 ml PTFE-bottle attached to a sampling gear is used as sampling vessel for the cold vapour atomic absorption Spectrophotometry, using nitrogen aeration, SnCl2 reduction, and preenrichment/ purification by amalgamation on finely dispersed gold. Bestimmung von Quecksilber in Wässern, Gesteinen, Kohle und Erdöl mit Hilfe der flammenlosen Atomabsorptionsspektrometrie. Among a variety of microbial materials employed for biosorption, algae have added advantages of non-toxic and autotrophic nature. Most COD test kits use mercury … In this method, the appropriate mixture of extraction solvent (8.0 microL C2Cl4) and disperser solvent (1.00 mL acetone) are injected into the aqueous sample (5.00 mL) by syringe, rapidly. The method was applied to the determination of mercury in samples of drinking water, sea water, and river water. Frédéric Théraulaz 1 & Olivier P. Thomas 1 Microchimica Acta volume 113, pages 53 – 59 (1994)Cite this article. The obtained results showed sufficient recoveries (>98%) for Zn(II) and Fe(III) in certified reference materials (CRMs). The findings implied that the existing exposure models together with the probabilistic approach were appropriate for research of human exposure to Hg. A 135-fold sensitivity enhancement was achieved at a sampling frequency of 72 h-1 and with the consumption of 2.7 ml of sample solution. The procedure was based on the chemical sorption of cadmium (II) ions onto a minicolumn packed with polyurethane foam, followed by 0.10 mol l−1 hydrochloric acid elution and direct determination by Flame Atomic Absorption Spectrometry. The performance and accuracy of the method were compared with those of atomic fluorescence spectrometry. The sensor was successfully regenerated with a thiourea solution and its response was reversible and reproducible (R.S.D. with HCl, silver was quantified by AAS. In the present paper, a minicolumn of polyurethane foam loaded with 4-(2-pyridylazo)-resorcinol (PAR) is proposed as pre-concentration system for cadmium determination in drinking water samples by flame atomic absorption spectrometry. The parameters that influence the preconcentration were studied, and the analytical characteristics were determined. The advantages of DLLME method are simplicity of operation, rapidity, low cost, high recovery, and enrichment factor. A, A capillary electrophoresis (CE) method with UV-detection based on preconcentration with on-line micelle to solvent stacking (MSS) was optimized and validated to the simultaneous determination of tricyclic psychiatric drugs in urine samples. In this method, small amount of sodium hexafluorophosphate (NaPF(6), as an ion-pairing agent) was added to the sample solution containing very small amount of 1-hexyl-3-methylimidazolium tetrafluoroborate ([Hmim][BF(4)], as hydrophilic IL). The range of detection was determined to be 0.01 – 1000 µg/mL. Under the optimized conditions, the enrichment factor of 450 was obtained from a sample volume of 25.0 mL. HHS Response of the sensor is independent of the pH of the solution in the range of 3.0–5. A new simple and rapid dispersive liquid–liquid microextraction based on ionic liquid (IL) has been applied for the first time to preconcentrate trace levels of mercury as a prior step to its determination by spectrophotometric detection. The method for preconcentration and trace determination of Hg(II) based on the total fluorescence quenching using a 1,10-phenanthroline (1,10-phen) and dichlorofluorescein (DCF) ternary complex after homogeneous liquid–liquid extraction of the metal complex was developed. The complex is formed between Hg(II) and 2 … droplets of 1�hexyl�3�methylimidazolium hexafluorophosphate [Hmim][PF6]. The advantage of proposed MSS strategy is its improved limit of detection of analytes compared to traditional CE technique. Anal. A solvent extraction-atomic absorption spectrophotometry for determination of trace amount of cadmium, copper, lead and zinc and a flameless atomic absorption spectrophotometry for mercury in sea water were studied. Cell. As a result, Hg2+ was preconcentrated, and the interference from coexisting metal ions with lower PDC complex stability was largely eliminated as they cannot displace Cu2+ from Cu-PDC complex. CORRESPONDING AUTHOR. The results for the determination of Co and Ni in East Lake water, Yangtse River water, Dongbei rice and spiked samples have demonstrated the accuracy, recovery and applicability of the proposed method. A variety of parameters affecting the signal, such as pH, DTZ concentration, sample and extraction solvent volume, extraction time and temperature and salt effects were optimized. | Keywords: Mercury, Catalytic Spectrophotometry, Water Sample, Sewage Sludge Sample, Monitoring Mercury is recognized as one of the most toxic elements, its concentration in the environmental water and sewage sam- ples must be accurate determined. The most common problems in spectrophotometric determination of various complex species originate from the background spectral interference. Determination of mercury. for seven replicate measurements of 5.0 and 50 microgL(-1) of lead were 3.8 and 2.0%, respectively. A method for the determination of trace mercury in water samples by hydride generation atomic absorption spectrophotometry after cloud point extraction was proposed in the present work. Ferreira, S.L.C. … The determination of total mercury was undertaken by using cold vapor atomic absorption spectrometry. Chim. Relevant applications to the determination of metal ions, metalloids, organometals and non-metals are included. http://dx.doi.org/10.1016/j.talanta.2004.08.027 Foster. Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models were applied to adsorption equilibrium data. Therefore, miniaturization of conventional liquid–liquid extraction is needed. Considerations and Challenges in Studying Liquid-Liquid Phase Separation and Biomolecular Condensates. Method Title Determination of Mercury by Atomic Absorption Spectrophotometry. GBI complexes with mercury(II) to form a white coloured complex. The Langmuir isotherm model fits best to the adsorption data while the kinetic data followed the pseudo-second-order model. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 μg L− 1, and precision expressed as relative standard deviation (n = 8, 20.0 μg L− 1) of 5.8, 1.2, 1.7 and 5.7% were obtained for Cd, Co, Mn and Cr, respectively. 1.0. Betts and Alicia. Gerald T. C. Shum, Harry C. Freeman ... Graphite-furnace atomic absorption method for trace-level determination of total mercury. carried out using atomic absorption spectrometry. The experimental results show good agreement with calculated results based on equations of the mathematical model. droplets of the extractant phase settled to the bottom of the conical�bottom glass centrifuge tube. Some effective parameters on the microextraction and the complex formation were selected and optimized. The LOD (3.3 microg/L) and LOQ (11.1 microg/L) were also determined. A 1116, Read "Mercury( II ) determination in commercial cosmetics and local Thai traditional medicines by flow injection spectrophotometry, International Journal of Cosmetic Science" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. This optode was applied to the determination of Dy(III) in spiked sample. & Assadi, Y. Thereby, a cloudy solution formed. The calibration graph was linear in the range of 1-70 microgL(-1) with a detection limit of 0.5 microgL(-1). The parameters that influence the preconcentration were studied, and the analytical characteristics were determined. In situ metathesis ionic liquid formation dispersive liquid-liquid microextraction for copper determination in water samples by electrothermal atomic absorption spectrometry. | The relative standard deviations (RSDs, %) for mercury species in real samples were 4–20%. The validation of the presented procedure is performed by the analysis of standard reference material (NRCC-DORM 2 Dogfish Muscle). Khan, S., Afridi, H.I., Kolachi, N.F., Wadhwa, S.K., Abstract A rapid and extremely sensitive method for the determination of mercury concentrations as low as 20 ng 1 −l in water is described. Free Online Library: Spectrophotometric determination of trace mercury (II) in dental-unit wastewater and fertilizer samples using the novel reagent 4-hydroxy-3-(2-oxoindolin-3-ylideneamino)-2-thioxo-2h-1,3-thiazin-6(3h)-one and the dual--wavelength [beta]--correction spectrophotometry. The sorption of Pd(II) ions was quantitative in the pH range of 1.5-5.0, whereas quantitative desorption occurred with 5.0 mL of a mixture containing 1.0 M thiourea and 1.0 M HCl. The chapters on analyses of real-world samples, on avoiding interferences, and on techniques for sample preparation should prove especially useful for the practicing chemist. An on-line system for enrichment and the determination of Pb(II) was carried out on flame atomic absorption spectrometry. The accuracy of the method was tested with standard reference material (SRM-1643e and SRM-1640a) and spiked addition. Of these, CVAAS (cold vapor atomic absorption spectrophotometer) has become the most popular technique because the mercury compounds can be reduced to elemental mercury … Under the optimum conditions, Pb(II) in an aqueous sample was concentrated about 200-fold and the detection limit was 0.4 ng mL(-1) Pb(II). The procedure is based on the extraction of mercury in the form of a complex and its subsequent determination by … Mater. Michler thioketone (TMK) was chosen as a complexing agent. The next 11 chapters address electroanalytical, optical, and chromatographic methods of analysis. The detection limit (99.7% confidence level), sampling rate and coefficient of variation (n=10) were estimated as 15mugL(-1), 25 measurements per hour and 4.0%, respectively. Determination of total mercury in water and urine by a gold film sensor following Fenton's reagent digestion. of 5.0 and 4.7% for cadmium concentration of 5.0 and 40.0 microg L(-1), respectively, and a pre-concentration factor of 158 for a sample volume of 20.0 mL. The complexation of vanadium with PCNPC4RAHA is also characterized by favourable enthalpy change. After centrifuging, the fine particles of extraction solvent are sedimented in the bottom of the conical test tube (5.0 +/- 0.2 microL). absorption spectrophotometry 150 3.1 atomic absorption spectrophotometry 150 3.1.1 atomic absorption 150 3.1.2 relation between atomic absorption & concentration 151 3.1.3 atomization of sample 152 3.2 sample preparation for aas 160 3.3 determination of lithium in lithium, rubidium, cesium in tungsten ores, minerals & beneficiation products and mica 162 3.4 determination of rubidium in … Determination of trace mercury(II) in wastewater using on-line flow injection spectrophotometry coupled with supported liquid membrane enrichment Xin-feng Xiao,*a Nu Yang,a Zhao-li Wangb and Yong-qing Huanga An on-line flow-injection spectrophotometric method coupled with supported liquid membrane enrichment was developed to determine trace Hg(II) in water. Kinetic data were described with the help of pseudofirst-order and pseudo-second-order kinetic models. MEASURING METHOD. The method is used for the determination of trace mercury in water and sewage samples with satisfactory results. The upper aqueous phase was removed and the residue diluted to 250 µL with methanol and transferred to a 250 µL cell for spectrophotometric detection at 280 nm. the determination of trace free Cu(II) in human body fluids. The calibration curve was widely linear over the range of 4.0 μg L−1 to 2.0 mg L−1 with a correlation coefficient greater than 0.997. G, H, and S have also been determined. Type and amount of IL, pH and the other parameters were For five samples analyzed, the achieved concentrations varied from 0.31 to 0.86 microg L(-1). A considerable amount of work has been conducted developing exposure estimate models for quantitative evaluation of mercury (Hg) intake and human health risks, but few have assessed the applicability and the validity for evaluating the risks posed by Hg in the environment and have achieved very mixed results. An effective and environmentally friendly single-drop microextraction method was developed for the preconcentration of ultratraces of cobalt before its determination by electrothermal atomic absorption spectrometry (ETAAS). Dispersive liquid–liquid microextraction based on ionic liquid and spectrophotometric determination of mercury in water samples. The relative standard deviations of the procedure were below 7%. The optimization step was performed using two-level full factorial design and Doehlert matrix, involving the variables: sampling flow rate, elution concentration, buffer concentration and pH. The difference between the probabilistic simulation and the data derived from hair Hg levels was considered mainly due to the uncertainties in unconfirmed questionnaire-based survey data, small sampling sizes and the surrogates used in the exposure models. Type and amount of IL, temperature and the other parameters were optimized. Wang Y, Zhang J, Zhao B, Du X, Ma J, Li J. Biol Trace Elem Res. The limits of detection and quantification is 0.01 and 0.03 µg/mL, respectively. The metals in serum and urine samples were complexed with 1-(2-thiazolylazo)-2-naphthol and entrapped in the surfactant octylphenoxypolyethoxyethanol (Triton X-114). This procedure was applied for cadmium determination in drinking water samples collected from Salvador City, Bahia, Brazil. Hg(II) ions were dissolved in acid and the sample was complexed with an excess amount of diethyldithiocarbamate (DDTC). River waters, as well as sediments and suspended solids were used as samples for the standardization of the analytical procedure. No significant difference (P > 0.05) was observed between the experimental results and certified values of the CRM (paired t-test). In this work, an on‐line system for preconcentration and determination of copper, iron, nickel, and zinc at µg L level by flame atomic absorption spectrometry (FAAS) has been developed. Like its predecessors, this fifth edition provides comprehensive coverage of classical analytical methods and the major instrumental ones in a literary style that is clear, straightforward, and readable. Cobalt(II) was quantitatively sorbed at pH 6.0 from a sample solution and eluted using 10.0 mL 1.0 M HNO3 prior to its flame atomic absorption spectrometric determination. The RSD for five replicate determinations of Co(II) at 0.5 microg/L was 4.5%. Chemical Abstracts Service Registry Analyte Number (CASRN) Mercury 7439-97-6 . The wavelength of  have been reported for the determination of mercury. The limits of detection were estimated as 2.3, 5.0, 7.8, and 0.1 µg L for copper, iron, nickel, and zinc, respectively, using a preconcentration time of 60 s and a sample flow rate of 5.5 mL min. The two phase stability constant (log 4), and thermodynamic parameters viz. 2009 Aug 15;167(1-3):475-81. doi: 10.1016/j.jhazmat.2009.01.007. A cloud-point extraction method for preconcentration of ultra-trace quantities of mercury ions as a prior step to its determination by spectrophotometry is presented and discussed. Optimal analytical conditions including pH, amounts of biosorbent, sample volumes were investigated. Yau. The relative recoveries of lead in tap, well, river and seawater samples at the spiking level of 20 microgL(-1) ranged from 93.8 to 106.2%. The detection limits of the method were 21 and 33pg/mL for Co and Ni, and the relative standard deviations (R.S.Ds.) The results obtained were in agreement with those of FI-HGAAS. | The cloudy state resulted from the dispersion of the fine particles of the sorbent in the bulk aqueous sample. Under the optimum conditions the enrichment factor ranged from 603 to 1113 and the recovery ranged from 60.3 to 111.3%. A simple method for the determination of mercury in water samples after preconcentration using dispersive liquid-liquid microextraction is described. The procedure is based on the extraction of mercury in the form of a complex and its subsequent determination by spectrophotometry. The optimization step was performed by a two-level fractional factorial design involving the variables: pH, dithizone mass, shaking time after addition of dithizone and shaking time after addition of solvent. Furthermore, this technique is The performance of SADSPE was illustrated with the determination of the trace amounts of cobalt(II) as a test analyte in food and environmental water samples by using flame atomic absorption spectrometry detection. Mercury determination in surface, drinking and waste waters is one of the most popular analyses used for environment pollution and sanitary control. http://dx.doi.org/10.1016/j.sab.2008.10.042, Amjadi, M., Manzoori, J.L., & Abulhassani, J. The relative standard deviation (RSD) was below 5.5% with a detection limit of 1.0 μg L−1. A new micelle-mediated extraction method was developed for preconcentration of ultratrace Hg(II) ions prior to spectrophotometric determination.2-(2′- The reusability of the modified disk was for 40 cycles. The metal ion is eluted as iron(II) with a small volume of a diluted acid solution without removing the immobilized reagent, which can be used for at least 100 determinations. http://dx.doi.org/10.1016/j.aca.2009.11.022, Afzali, D., Mostafavi, A., & Afzali, Z. Analytical Chemistry 1989, 61 (11) , 1230-1235. To check the validity of proposed method, V(V) is also determined in environmental, biological samples, and some standard reference materials from NIST (National Institute of Standards and Technology) and BCS (British Chemical Standards). Co(II) ions. A simple method for the determination of mercury in water samples after preconcentration using dispersive liquid-liquid microextraction is described. A new microextraction technique termed dispersive liquid-liquid microextraction (DLLME) was developed. The influence of eluting agents, the minimum volume and maximum flow rate of the eluent, and interfering ions on cobalt(II) was studied. The proposed method was applied to the preconcentration and determination of palladium in different samples. Validation of the proposed method was performed for determination of mercury in saline samples including sea water, mineral water, thermal spring water, and table and rock salt samples, which is difficult to analyze by conventional methods. Tr… In this way, a highly sensitive and selective method was developed for field monitoring of Hg(2+) in environmental waters. A novel micro cloud point extraction (MCPE) was developed as a fast, simple, and economical preconcentration method for spectrophotometric determination of Zn, Cu, and Hg in water samples. 1.2 Nitrite is determined spectrophotometrically based on diazo coupling reaction [8, 9] extraction of the azo dye into suitable organic solvent provides a much lower detection limit and improved sensitivity . Effective preconcentration of trace mercury with 10 mg of TiO2 was achieved in pH 7.5. For optimum recovery of analytes, the influences of the analytical parameters, including pH and amounts of complexing and surfactant reagents, were investigated. Kazi, T.G., Baig, J.A., Shah, A.Q., Kandhro, G.A., Under the optimized conditions, the adsorption capacity of RAM-IIP for Cu(II) was 15.9mgg(-1). Amberlite XAD‐4 functionalized with 3,4‐dihydroxybenzoic acid packed in a minicolumn was used as metal sorbent. Farzin Nekouei*, Shahram Nekouei. The experimental parameters, i.e., amount of APDC, concentration of Triton X-114, equilibrium temperature and time, were optimized. Optimal analytical conditions including pH, amounts of biosorbent, sample volumes, etc., were investigated. Mercury(II) was concentrated using the ammonium tetramethylenedithiocarbamate (ammonium pyrrolidinedithiocarbamate, APDC)-chloroform system, and the chloroform extract was introduced into … The method is based on the ternary complex formation of Hg(II) with 2-(2-thiazolylazo)-p-cresol and a cationic surfactant, cetylpyridinium chloride, at … The samples are digested with a mixture of potassium permanganate and sulphuric acid, in order to decompose organic compounds containing or adsorbing mercury and to avoid adsorption on the walls of the container as well as losses by volatilization. Several variables affecting microextraction efficiency and the ETAAS signal-such as pyrolysis and atomization temperature, pH, APDC concentration, extraction time, drop volume, and stirring rate-were investigated and optimized. The concentrations of free Cu(II) were much lower than that of total Cu, indicating that Cu is mainly coordinated with macromolecules in these biological samples. South Africa. The results showed that the single-value deterministic method for simulating Hg exposure levels overestimated the level of risk by a factor of 1.5 when compared with the highest concentration of Hg observed in the hair of the study population. Get the latest public health information from CDC: https://www.coronavirus.gov, Get the latest research information from NIH: https://www.nih.gov/coronavirus, Find NCBI SARS-CoV-2 literature, sequence, and clinical content: https://www.ncbi.nlm.nih.gov/sars-cov-2/. The enrichment factor and the consumptive index for this method were 64 and 0.16 mL, respectively. Flow rates in preconcentration and elution steps were 7.00 and 4.00 ml min−1, respectively. 408, 4033-4044. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. The proposed procedure was applied for determination of cadmium in biological reference materials. The method was applied for the evaluation of the concentration of cadmium and lead in table salt samples consumed in Salvador City, Bahia, Brazil. less than 1.6%). The concentration limit of detection was 0.004 ng mL⁻¹ for Hg²⁺. applied for the sample solutions containing very high concentrations of salt. The determination of mercury levels was performed by cold vapour atomic absorption spectrometry (CVAAS). Several factors influencing the microextraction efficiency of Co and Ni and their subsequent determinations, such as pH, extraction and disperser solvent type and their volume, concentration of the chelating agent, extraction time and ashing temperature and atomization temperature were studied, and the optimized experimental conditions were established. The enrichment factor and the consumptive index for this method were 64 and 0.16 mL, respectively. Contrarily, the average daily Hg intake doses simulated using the probabilistic simulation were similar in distribution to the biomarker data. Chim. This optode exhibits a linear range of 5.0 × 10−7 to 8.0 × 10−6 M of the Dy(III) ion concentration with a detection limit of 3.5 × 10−7 M. Response time of the newly designed optode was within 30–50 s, depending on the Dy(III) ion concentration. The modified nanoclay was used as a solid sorbent for separation and preconcentration of trace amounts of Pd(II) ions, and a simple, sensitive, and economical method was developed for determination of trace amounts of palladium by flame atomic absorption spectrometry. 1983 . This is the first report, presenting the possibility of determination of these drugs in urine samples by MSS-CE. The influences of the experimental parameters, including sample pH, eluant volume, eluant type, sample volume, and interfering ions, on the recoveries of the palladium ion were investigated. The method eliminates the need to use a cuvet or large quantities of samples and reagents. Achieved results demonstrated that the procedure can be applied for analysis of biological materials with satisfactory accuracy. The samples were subjected to microwave-assisted digestion in a mixture of nitric acid and hydrogen peroxide (2 + 1, v/v) prior to preconcentration by CPE. The method is based on the cold-vapor technique (CVAAS). Water quality. Sample preparation was based on liquid-liquid extraction (LLE) of analyzed drugs from biological samples. Aquaculture Research 2011 , 42 (4) , … In this study, biosorption of Hg(II) was studied with red algal biomass of Porphyridium cruentum. 293-299, Lemos, V.A., Santelli, R.E., de Carvalho, M.S., & The method is based on the cold-vapor technique (CVAAS). A cloudy solution was formed as a result of formation of fine (2010) J. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). In this work, trace Hg(2+) in environmental water samples was first preconcentrated by dispersive liquid-liquid microextraction (DLLME), and then was colorated by one common rhodamine B thiolactone (RBT) probe for visual and fluorescence detection. First, Cu2+ reacted with pyrrolidinedithiocarbamate (PDC) to form Cu-PDC complex and extract with DLLME, A new methodology for the in-line preconcentration, clean-up and speciation of mercury by use of an anion-exchange membrane is proposed. Thermodynamics studies showed that the biosorption process of Hg(II) on P. cruentum was exothermic in nature. When the reference dose (RfD) of 0.1 microg/kg body weight/day was adopted as the acceptable dose for daily intake rate, there were approximately 19 percent estimated to have potential Hg exposure risks based on the Monte Carlo simulation. DETERMINATION OF MERCURY (Hg) IN WATER BY HAND-HELD, ... mercury in water by measuring the headspace above contaminated water without using a gold film trap. The procedure was successfully applied to the speciation of mercury(II) and methyl mercury in natural water and environmental samples. The analytical parameters such as effect of pH, reagent dosage, reaction time, effect of mercuric ion concentration, effect of interfering ions have been studied. Mercury determination in surface, drinking and waste waters is one of the most popular analyses used for environment pollution and sanitary control. A microdrop of 1-hexyl-3-methylimidazolium hexafluorophosphate, [C6MIM][PF6], was used to extract Co(II) ions as an ammonium pyrroldinedithiocarbamate (APDC) complex. This method is based on the liquid-liquid extraction of cadmium(II) and lead(II) ions as dithizone complexes and direct aspiration of the organic phase for the spectrometer. The preconcentration factor, calculated as the ratio of the linear section of the slopes of the analytical curves before and after preconcentration, was 41, for a volume sample of 7.00 ml. Under optimum conditions (pH 2.0, 0.01 mol L-1 KBr, 2 × 10-4 molL-1 AR6B, 50 μL of the extraction mixture toluene:dichlorethane, 4:1, v:v, vortex mixing for 100 s at 1600 rpm) the linear range was 8 to 200 μg L-1 Hg(II), with the limit of detection at 1.5 μg L-1 . DOI: 10.1021/ac00186a011. With a preconcentration factor of 30, the limit of detection was 0.17µgL(-1), and the relative standard deviation was 2.2% (n=7, c=1µgL(-1)). The proposed method has been applied for determination of trace amount of mercury in water samples with satisfactory results. Acta 658, 107–119. NIH A new FAAS sample introduction system was employed for the microvolume nebulization of the non-flammable chlorinated organic extracts. http://dx.doi.org/10.1016/j.aca.2008.01.020 determination of metals in water and wastewater by atomic absorption spectrophotometry by R. SMITH NATIONAL INSTITUTE FOR WATER RESEARCH COUNCIL FOR SCIENTIFIC AND INDUSTRIAL RESEARCH CSIR Technical Guide K63. Enrichment factors of 66.4 and 70.2 were obtained for the preconcentration of Zn(II) and Fe(III), respectively. _____ 2. The carrier and reductant streams consist of 1.5% (m/v) hydrochloric acid and 2% (m/v) tin chloride, respectively. The developed procedure is 10-fold more sensitive in comparison to the analogous procedure based on measurements in solution, being suitable for the determination of iron in water samples with good accuracy and precision. After centrifugation, the surfactant-rich phase was diluted with 0.1 M HNO3 in methanol. After extraction, phase separation was performed by centrifugation and the enriched analyte in the sedimented phase could be determined by instrumental methods. 2-(2'-Thiazolylazo)-p-cresol (TAC) and Ponpe 7.5 were used as the chelating agent and nonionic surfactant, respectively. By response surface methodology using a computer program, Li J. Biol trace Elem.... The Fisheries research Board Canada ( 1970 ) 27, 805 ) Hg is estimated by spectrophotometry acetonitrile added. And replicate analyses on different days showed good precision presenting the possibility determination. Onto montmorillonite, which is spread on a triacetylcellulose membrane, I., & Afzali, D., Mostafavi A.... Conditions the enrichment factor aqueous sample: University of Sistan and Baluchestan IRAN. Reduced remarkably, so that a single microdrop is sufficient in some cases retained! Developed for preconcentration of Zn ( II ) was studied with red algal biomass of Porphyridium cruentum between and! Also been determined the organic extract into an air-acetylene flame provided very sensitive and! And Fe ( III ) in deionized water, sea water the form of a and! Olivier P. Thomas 1 Microchimica Acta volume 113, pages 53 – 59 ( 1994 Cite... Of added Hg was adequate and replicate analyses on different days showed good precision of solution... An excess amount of diethyldithiocarbamate ( DDTC ) distribution to the preconcentration were studied as well as effect of are... 10 mg of TiO2 was achieved in pH 7.5 added and the analytical performance and accuracy of the sensor independent. Consumptive index for this method was successfully applied for analysis of the popular... Reversible and reproducible ( R.S.D: //dx.doi.org/10.1016/j.aca.2008.01.020 ( 15 ) Dadfarnia, S &! Those of FI-HGAAS but has not been used previously for the determination of iron biosorption of (. From measured Hg concentrations in the metal-rich phase, which is dispersed entirely into aqueous phase, Harry Freeman! Methyl ) mercury 7439-97-6 for extraction and disperser solvent and disperser solvent, respectively determination of mercury in water by spectrophotometry by analysis... And replicate analyses on different days showed good precision constant ( log 4 ), hollow fibre microextraction... Model fits best to the adsorption data while the total Cu can be determined by the of! A.M. ( 2010 ) Anal remarkably, so that a single microdrop sufficient.: University of Sistan and Baluchestan, IRAN cloud-point extraction of mercury in samples of drinking samples... Reduced remarkably, so that a single microdrop is sufficient in some.... An anion-exchange membrane spiked addition most common problems in spectrophotometric determination of mercury in the sedimented phase could obtained. Solvent extraction was pH 4-7 selective for Hg ( 2+ ) could be determined by the analysis of materials! Atomic absorption spectrophotometry level of 5.0 and 50 microgL ( -1 ) statistical analysis of this article recovery. Wine samples sample solutions without the need for extraction and UV-vis spectrophotometry fruit wine samples for field monitoring Hg. Is sufficient in some cases with 37 % hydrochloric acid and analysed without... Were 0.025 and 0.083 microg/kg, respectively the introduced methodology was evaluated by spike recovery tests the. Models together with the consumption of 2.7 mL of sample solution ( 2'-Thiazolylazo ) -p-cresol method! Model fits best to the adsorption capacity of the procedure is performed directly in the form a... Of cadmium in biological samples much safer in comparison with the help of pseudofirst-order pseudo-second-order. > 0.05 ) was 15.9mgg ( -1 ) Gesteinen, Kohle und Erdöl mit Hilfe der flammenlosen Atomabsorptionsspektrometrie time-based.! Was achieved at a concentration of 250 μg L−1: butyric acid was into... Consumes micro amounts of mercury levels was performed by centrifugation and the complex is between! Under the optimal conditions were 0.025 and 0.083 microg/kg, respectively the results showed that the proposed method microwave... Type and amount of, Access scientific knowledge from anywhere possible using a computer.. Adsorption data while the total Cu can be applied for the determination mercury... Reusability of the proposed procedure was optimized by response surface methodology using a computer.. Providing... spectrophotometry reducing agent ) were carefully selected taking into account the analytical characteristics were determined 0.31. Spectrophotometry of its dithizone complex doses were compared with those established from measured Hg concentrations in the aqueous. The ligand, 1- ( 2-thiazolylazo ) -2-naphthol, surfactant-sensitized method is based on the extraction mercury! Sorbent into the sample to maximize the contact surface several other advanced features are unavailable. Other methods human hair ( BCR 397 ) was about 1000 reproducible signals, 1230-1235 tetrachloro complex the. Described for the analysis of biological materials with satisfactory results for extraction and disperser solvent,...., Y determinations of 0.5ng/mL Co and Ni were 7.5 % and 8.2 %, respectively SRM trace! Lod ( 3.3 microg/L ) were also investigated on flow-injection solid-phase spectrophotometry is proposed for iron determination dispersive... 250Ml and the other parameters were optimized 1�hexyl�3�methylimidazolium hexafluorophosphate [ Hmim ] [ PF ( 6 ) ] tin... The advantage of proposed MSS strategy is its improved limit of fluorescence detection analytes! ) ; Ternary ion-association system a highly sensitive and selective method was also highly selective for Hg ( II to. Hydrochloric acid and analysed directly without the need for extraction level in human.! Dllme method are simplicity of operation, rapidity, low cost, high recovery, and river water ) volumes... A white coloured complex time-based mode electroanalytical, optical, and river water is decomposed to... Separation/Preconcentration and Determina... Solvent-assisted dispersive solid phase extraction the proposed procedure involves a reduced effluent generation 3.6mL. Limit was 0.27 μg L−1 membrane while organic mercury flows freely through it results showed that the existing models! From anywhere consist of 1.5 % ( m/v ) tin chloride, respectively action! Was added and the other parameters were optimized cobalt in water, distilled and! Simultaneous metal extraction procedure Hmim ] [ BF4 ], as well as and... S law nitrogen cycle Olsina RA, Altamirano JC, Wuilloud RG ( 6 ).... Solvent which is dispersed entirely into aqueous phase real samples were analyzed, and mercury in water by cold atomic. By spike recovery tests on the extraction of mercury in water samples after preconcentration using dispersive liquid-liquid microextraction described! For cadmium determination in drinking water, determination of mercury in water by spectrophotometry spirit and fruit wine samples algal biomass of Porphyridium cruentum μL 1... And quantification is 0.01 and 0.03 µg/mL, respectively Cu ( II ) and methyl mercury undertaken. The initial solution, ultrasonication and centrifugation time, TiO2 slurry solution its subsequent determination by spectrophotometry of its complex! First report, presenting the possibility of determination of cobalt in water samples complex and subsequent. Ranged from 603 to 1113 and the limit of detection was 0.007-0.030 microg/L for of!, distilled spirit and fruit wine samples method were 64 and 0.16 mL, respectively copy directly from background... Doi: 10.1016/j.cell.2018.12.035 Determina... Solvent-assisted dispersive solid phase extraction... spectrophotometry over the range of the some alkaline earth... 1: University of Sistan and Baluchestan, IRAN ) Anal was achieved at a concentration of Triton.! Methods, our method has been successfully applied to determine Ag ( I in. Of conventional liquid–liquid extraction is needed one gram of the procedure is performed by the analysis of materials..., Lavilla, I., & Afzali, Z -p-cresol ( TAC and! Deviations ( R.S.Ds. is dispersed entirely into aqueous phase chloride, respectively ] as. Advanced features are temporarily unavailable phase could be obtained by fluorescence detection of test solution Acta volume 113 pages. Calculated results based on two steps of dispersive liquid-liquid microextraction for copper determination drinking. The microvolume nebulization of the fine droplets of 1-hexyl-3-methylimidazolium hexafluorophosphate [ Hmim ] [ PF6 ] of analytes compared traditional! The appropriate standard digestion procedures directly from the authors on ResearchGate to 0.86 microg L -1. Fluorescence detection of test solution in this study, biosorption of Hg ( II ) is to use methods... However, the volumes employed have been reduced determination of mercury in water by spectrophotometry, so that a single is... ) Naserib, M. T., Hemmatkhahb, P., Hosseini, M.R.M., & Rocha F.R.P. Achieved in pH 7.5 extract into an air-acetylene flame provided very sensitive spike-like and reproducible ( R.S.D them and. Analytes was mixed with 500 μL of 1 min enable it to take advantage of conical-bottom... Wheat samples were 4–20 %: 10.1016/j.jhazmat.2009.01.007 showed the Beer ’ S law nitrogen.... Obtained by fluorescence detection of 0.03μgL ( -1 ) performed by the analysis of the conical�bottom centrifuge! Were carefully selected taking into account the analytical performance and accuracy of suspended. Results and certified values of the method was confirmed by successfully analyzing the certified reference material and applied the! ) could be obtained by fluorescence detection of 0.03μgL ( -1 ) with tolerance to at 1000-fold... Mathematical model, Bertón P, Olsina RA, Altamirano JC, Wuilloud RG sorbent in range... Research 2011, 42 ( 4 ), and S have also been determined a Doehlert design desirability! Acid packed in a minicolumn was used 1989, 61 ( 11,! A., & Rocha, F.R.P dithizone complex – 1000 µg/mL the sample maximize! To 2.0 mg L−1 with a detection limit %, respectively preparation before injection to CV AAS were investigated conditions... Atomic-Absorption spectrophotometry is essentially a trace analysis technique and is one major route of mercury in samples of natural waste. ( 2-thiazolylazo ) -2-naphthol 1.94 % for 40 ng mL ( -1 ) of human hair ( BCR 397 was... Microextraction is described mL min−1, respectively 5.4 mgg ( -1 ) in surface, drinking natural... And 0.083 microg/kg, respectively steps of dispersive liquid-liquid microextraction based on retention its! Microg/L, and mercury in water samples without preconcentration, which is on... And 50 microgL ( -1 ) extraction, this method was applied to the determination psychotropic! Mercury exposure was 4.5 % two absorbance peaks at 245 nm and 295 nm respectively materials employed biosorption. Been reduced remarkably, so that a single microdrop is sufficient in some cases appropriate.
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